This chic 17th-century palazzo – a perfect fusion of old and new – is Tuscany's luxury address and deliciously boutique to boot. After a day spent sightseeing, its gorgeous interior courtyard, conservatory and beautifully appointed, classically elegant rooms – each different, with sumptuous marble bathrooms – are clearly designed for relaxing and pampering. The finest have canopy beds resting romantically beneath centuries-old frescoed ceilings.
Check its website for last-minute rates.